Publication: Light‐activated carbon monoxide prodrugs based on bipyridyl dicarbonyl ruthenium(II) complexes
Light‐activated carbon monoxide prodrugs based on bipyridyl dicarbonyl ruthenium(II) complexes
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Geri, S., Krunclova, T., Janouskova, O., Panek, J., Hruby, M., Hernández‐Valdés, D., Probst, B., Alberto, R. A., Mamat, C., Kubeil, M., & Stephan, H. (2020). Light‐activated carbon monoxide prodrugs based on bipyridyl dicarbonyl ruthenium(II) complexes. Chemistry, 26(48), 10992–11006. https://doi.org/10.1002/chem.202002139
Abstract
Abstract
Abstract
Two photoactivatable dicarbonyl ruthenium(II) complexes based on an amide‐functionalised bipyridine scaffold (4‐position) equipped with an alkyne functionality or a green‐fluorescent BODIPY (boron‐dipyrromethene) dye have been prepared and used to investigate their light‐induced decarbonylation. UV/Vis, FTIR and 13C NMR spectroscopies as well as gas chromatography and multivariate curve resolution alternating least‐squares analysis (MCR‐ALS) were used to elucidate the mechanism of the decarbonylation process. Release of the first CO m
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- Geri, Stepan
- Krunclova, Tereza
- Janouskova, Olga
- Panek, Jiri
- Hruby, Martin
- Hernández‐Valdés, Daniel
- Mamat, Constantin
- Kubeil, Manja
- Stephan, Holger
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Geri, S., Krunclova, T., Janouskova, O., Panek, J., Hruby, M., Hernández‐Valdés, D., Probst, B., Alberto, R. A., Mamat, C., Kubeil, M., & Stephan, H. (2020). Light‐activated carbon monoxide prodrugs based on bipyridyl dicarbonyl ruthenium(II) complexes. Chemistry, 26(48), 10992–11006. https://doi.org/10.1002/chem.202002139
