Publication: Transition metal-free amination of aryl halides-A simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines
Transition metal-free amination of aryl halides-A simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines
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Bolliger, J. L., & Frech, C. M. (2009). Transition metal-free amination of aryl halides-A simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines. Tetrahedron, 65(6), 1180–1187. https://doi.org/10.1016/j.tet.2008.11.072
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Abstract
A simple and reliable reaction protocol for the clean, fast, and high-yielding synthesis of various N-arylated amines derived from reactions of aryl halides with various (also sterically hindered) amines under transition metal-free reaction conditions is presented. Dioxane and KN(Si(CH3)3)2 were found to be the ideal solvent and base for this transformation. The conversion rates and yields observed are excellent and in the majority of the reactions performed significantly higher than that obtained in their catalyzed versions. Furtherm
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- Bolliger, J L
- Frech, C M
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Bolliger, J. L., & Frech, C. M. (2009). Transition metal-free amination of aryl halides-A simple and reliable method for the efficient and high-yielding synthesis of N-arylated amines. Tetrahedron, 65(6), 1180–1187. https://doi.org/10.1016/j.tet.2008.11.072