Publication: Nuclearity manipulation in Schiff-base fac -tricarbonyl complexes of Mn(I) and Re(I)
Nuclearity manipulation in Schiff-base fac -tricarbonyl complexes of Mn(I) and Re(I)
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Mokolokolo, P. P., Frei, A., Tsosane, M. S., Kama, D. V., Schutte-Smith, M., Brink, A., Visser, H. G., Meola, G., Alberto, R., & Roodt, A. (2018). Nuclearity manipulation in Schiff-base fac -tricarbonyl complexes of Mn(I) and Re(I). Inorganica Chimica Acta, 471, 249–256. https://doi.org/10.1016/j.ica.2017.10.036
Abstract
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Abstract
A range of bidentate Schiff-base ligands, 2-(cyclohexyliminomethyl)phenol, 2-(cyclopentyl)methyl-5-methylphenol and 5-methyl-2-(phenylethyliminimethyl)phenol, with a variation in steric and electronic properties, were synthesized and coordinated to the fac-{MI(CO)3}+ core (M = Mn, Re). It is illustrated that the nuclearity for the rhenium complexes may be manipulated, i.e., either mono- or dinuclear complexes may be synthesized using virtually the same ligands and synthetic procedures. However, only dinuclear structures were isolated
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- Mokolokolo, Pennie P
- Frei, Angelo
- Tsosane, Mampotso S
- Kama, Dumisani V
- Schutte-Smith, Marietjie
- Brink, Alice
- Visser, Hendrik G
- Meola, Giuseppe
- Roodt, Andreas
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Mokolokolo, P. P., Frei, A., Tsosane, M. S., Kama, D. V., Schutte-Smith, M., Brink, A., Visser, H. G., Meola, G., Alberto, R., & Roodt, A. (2018). Nuclearity manipulation in Schiff-base fac -tricarbonyl complexes of Mn(I) and Re(I). Inorganica Chimica Acta, 471, 249–256. https://doi.org/10.1016/j.ica.2017.10.036