Publication: Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling
Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling
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Wei, X., Shu, W., García-Domínguez, A., Merino, E., & Nevado, C. (2020). Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling. Journal of the American Chemical Society, 142(31), 13515–13522. https://doi.org/10.1021/jacs.0c05254
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Alkene dicarbofunctionalizations enable the streamlined construction of aliphatic structures and have thus been the subject of intense research efforts. Despite significant progress, catalytic asymmetric variants remain scarce. Inspired by the advantages of reductive cross-coupling approaches, we present here a highly efficient asymmetric intermolecular Ni-catalyzed reductive dicarbofunctionalization of alkenes. Two distinct readily available electrophiles, namely, Csp2- and Csp3-halides, are added simultaneously across a variety of o
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- Wei, Xiaofeng
- Shu, Wei
- García-Domínguez, Andrés
- Merino, Estíbaliz
- Nevado, Cristina
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Wei, X., Shu, W., García-Domínguez, A., Merino, E., & Nevado, C. (2020). Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling. Journal of the American Chemical Society, 142(31), 13515–13522. https://doi.org/10.1021/jacs.0c05254
