Publication: Total Synthesis of the Polyoxygenated Sesquiterpenes Guignarderemophilanes C and D
Total Synthesis of the Polyoxygenated Sesquiterpenes Guignarderemophilanes C and D
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Ilazi, A., Liffert, R., & Gademann, K. (2018). Total Synthesis of the Polyoxygenated Sesquiterpenes Guignarderemophilanes C and D. Helvetica Chimica Acta, 101, e1800011. https://doi.org/10.1002/hlca.201800011
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Abstract
The total syntheses of the neural anti‐inflammatory agents guignarderemophilanes C and D have been accomplished for the first time starting from γ‐hydroxy carvone in 15 and 14 steps, respectively. The presented synthetic route proceeds via a known intermediate, whose synthesis has been elaborated in our group in the course of the total synthesis of the sesquiterpenoid periconianone A. Key for the successful conversion of this intermediate into both targets was finding a suitable strategy to install the 1,2,3‐trihydroxylated A‐ring sca
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- Ilazi, Agron
- Liffert, Raphael
- Gademann, Karl
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Ilazi, A., Liffert, R., & Gademann, K. (2018). Total Synthesis of the Polyoxygenated Sesquiterpenes Guignarderemophilanes C and D. Helvetica Chimica Acta, 101, e1800011. https://doi.org/10.1002/hlca.201800011
