Publication: Conformations of an amino–amido–thiolate self-assembled layer on gold in air and in electrolytes
Conformations of an amino–amido–thiolate self-assembled layer on gold in air and in electrolytes
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Bittner, A. M., Epple, M., Kuhnke, K., Houriet, R., Heusler, A., Vogel, H., Seitsonen, A. P., & Kern, K. (2003). Conformations of an amino–amido–thiolate self-assembled layer on gold in air and in electrolytes. Journal of Electroanalytical Chemistry, 550–55, 113–124. https://doi.org/10.1016/S0022-0728(03)00136-0
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The amino-amido-thiol AT (HS-(CHZ)(10)-CO-NH-CHz-CHZ-NH2), adsorbed on Au(111), was studied by sum frequency generation (SFG) and infrared reflection absorption spectroscopy in the CHZ stretching vibration region. The SFG and infrared spectra are qualitatively similar; both show the symmetric stretching band and an intense and unusually broad antisymmetric stretching band. The infrared spectra show a reversible difference between a sample dried after rinsing in electrolyte and dried after rinsing in ethanol, thus exhibiting a `solvent
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Bittner, A. M., Epple, M., Kuhnke, K., Houriet, R., Heusler, A., Vogel, H., Seitsonen, A. P., & Kern, K. (2003). Conformations of an amino–amido–thiolate self-assembled layer on gold in air and in electrolytes. Journal of Electroanalytical Chemistry, 550–55, 113–124. https://doi.org/10.1016/S0022-0728(03)00136-0