Publication: Cycloparaphenylene Double Nanohoop: Structure, Lamellar Packing, and Encapsulation of C60 in the Solid State
Cycloparaphenylene Double Nanohoop: Structure, Lamellar Packing, and Encapsulation of C60 in the Solid State
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Yang, Y., Huangfu, S., Sato, S., & Juricek, M. (2021). Cycloparaphenylene Double Nanohoop: Structure, Lamellar Packing, and Encapsulation of C60 in the Solid State. Organic Letters, 23(20), 7943–7948. https://doi.org/10.1021/acs.orglett.1c02950
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A new member of the cycloparaphenylene double-nanohoop family was synthesized. Its π-framework features two oval cavities that display different shapes depending on the crystallization conditions. Incorporation of the peropyrene bridge within the nanoring cycles via bay-regions alleviates steric effects and thus allows 1:1 complexation with C60 in the solid state. This nanocarbon adopts a lamellar packing motif, and our results suggest that the structural adjustment of this double nanohoop could enable its use in supramolecular and se
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- Yang, Yong
- Huangfu, Shangxiong
- Sato, Sota
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Yang, Y., Huangfu, S., Sato, S., & Juricek, M. (2021). Cycloparaphenylene Double Nanohoop: Structure, Lamellar Packing, and Encapsulation of C60 in the Solid State. Organic Letters, 23(20), 7943–7948. https://doi.org/10.1021/acs.orglett.1c02950
