Publication: Cation-Deficient Ce-Substituted Perovskite Oxides with Dual-Redox Active Sites for Thermochemical Applications
Cation-Deficient Ce-Substituted Perovskite Oxides with Dual-Redox Active Sites for Thermochemical Applications
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Naik, J. M., Bulfin, B., Triana, C. A., Stoian, D. C., & Patzke, G. R. (2023). Cation-Deficient Ce-Substituted Perovskite Oxides with Dual-Redox Active Sites for Thermochemical Applications. ACS Applied Materials & Interfaces, 15(1), 806–817. https://doi.org/10.1021/acsami.2c15169
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Identifying thermodynamically favorable and stable non-stoichiometric metal oxides is of crucial importance for solar thermochemical (STC) fuel production via two-step redox cycles. The performance of a non-stoichiometric metal oxide depends on its thermodynamic properties, oxygen exchange capacity, and its phase stability under high-temperature redox cycling conditions. Perovskite oxides (ABO3−δ) are being considered as attractive alternatives to the state-of-the-art ceria (CeO2−δ) due to their high thermodynamic and structural tunab
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162435
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Design of perovskite and doped-ceria redox materials for high performance solar thermochemical splitting of H2O and CO2
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Naik, J. M., Bulfin, B., Triana, C. A., Stoian, D. C., & Patzke, G. R. (2023). Cation-Deficient Ce-Substituted Perovskite Oxides with Dual-Redox Active Sites for Thermochemical Applications. ACS Applied Materials & Interfaces, 15(1), 806–817. https://doi.org/10.1021/acsami.2c15169