Publication: Synthesis and reactivity of the rhenium fulvene sandwich complex [Re(η6-C5H4CH2)(η6-C6H6)]+
Synthesis and reactivity of the rhenium fulvene sandwich complex [Re(η6-C5H4CH2)(η6-C6H6)]+
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Suremann, N. F., Meola, G., Blacque, O., Braband, H., & Alberto, R. (2020). Synthesis and reactivity of the rhenium fulvene sandwich complex [Re(η6-C5H4CH2)(η6-C6H6)]+. Organometallics, 39(14), 2713–2718. https://doi.org/10.1021/acs.organomet.0c00313
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We present the synthesis of the first mixed-ring rhenium fulvene sandwich complex, [Re(η6-C5H4CH2)(η6-C6H6)]+, from the respective carbinol precursor [Re(η5-C5H4CH2OH)(η6-C6H6)]. The demanding preparation on the basis of the reactive cross-conjugated π system of the fulvene ligand restricts the synthetic accessibility for such fulvene complexes, and the only pathways elaborated originate from the respective carbinols. In contrast to related systems, a suitable rhenium-containing precursor did not exist hitherto. Recently, we described
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- Suremann, Nina F
- Meola, Giuseppe
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Suremann, N. F., Meola, G., Blacque, O., Braband, H., & Alberto, R. (2020). Synthesis and reactivity of the rhenium fulvene sandwich complex [Re(η6-C5H4CH2)(η6-C6H6)]+. Organometallics, 39(14), 2713–2718. https://doi.org/10.1021/acs.organomet.0c00313
