Publication: Carbonyliron Complexes of Allenic Acids, Esters, Amides, and Imides
Carbonyliron Complexes of Allenic Acids, Esters, Amides, and Imides
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Trifonov, L. S., Orahovats, A. S., & Heimgartner, H. (1990). Carbonyliron Complexes of Allenic Acids, Esters, Amides, and Imides. Helvetica Chimica Acta, 73, 1734–1741. https://doi.org/10.1002/hlca.19900730619
Abstract
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Abstract
On irradiation in the presence of Fe(CO)5, the allenic amides and imides showed a similar course of complexation to that of esters and lactones, respectively, e.g. the amides of type 10 led to diiron complexes of type 11 (Scheme 3 ), whereas the imide 12 yielded a mixture of a dinuclear and two mononuclear complexes (13-15, Scheme 4). The racemic ester 6 also gave mononuclear (7a, 7b, and 9) and dinuclear complexes (8a and 8b; Scheme 2). In case of the allenic acid 4, only complexation of type 5 was observed (Scheme 1).
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- Trifonov, Latchezar S
- Orahovats, Alexander S
- Heimgartner, Heinz
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Trifonov, L. S., Orahovats, A. S., & Heimgartner, H. (1990). Carbonyliron Complexes of Allenic Acids, Esters, Amides, and Imides. Helvetica Chimica Acta, 73, 1734–1741. https://doi.org/10.1002/hlca.19900730619
