Publication: An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template
An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template
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Alzeer, J., Roth, P. J. C., & Luedtke, N. W. (2009). An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template. Chemical Communications, 15, 1970–1971. https://doi.org/10.1039/b822985f
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Abstract
The templating effects of strongly coordinating ions like Co(II), Cu(II), and Zn(II) can dramatically improve the yields of phthalocyanine synthesis. The main problem with this approach is the lack of reported conditions for the subsequent removal of such ions to generate metal-free phthalocyanines. During our synthesis of guanidine-containing phthalocyanines we discovered a new demetallation reaction that, to the best of our knowledge, provides the first examples of Zn(II) removal without destroying the phthalocyanine itself. This de
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- Roth, P J C
- Luedtke, N W
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Alzeer, J., Roth, P. J. C., & Luedtke, N. W. (2009). An efficient two-step synthesis of metal-free phthalocyanines using a Zn(II) template. Chemical Communications, 15, 1970–1971. https://doi.org/10.1039/b822985f
