Publication:

Water soluble phosphine rhenium complexes

Date

Date

Date
2010
Journal Article
Published version

Citations

Citation copied

Maccaroni, E., Dong, H., Blacque, O., Schmalle, H. W., Frech, C. M., & Berke, H. (2010). Water soluble phosphine rhenium complexes. Journal of Organometallic Chemistry, 695(4), 487–494. https://doi.org/10.1016/j.jorganchem.2009.11.031

Abstract

Abstract

Abstract

Reduction of NMe4](2)ReBr5(NO)] (1) with zinc in acetonitrile leads to the known trisacetonitrile compound ReBr2(CH3CN)(3)(NO)] (2). Attempts to turn 2 into a dihydrogen or a hydride complex applying direct reaction with H-2 or with H-2 and a base were unsuccessful. Complex 2 could be transformed into ReBr(BF4)mer(CH3CN)(3)(NO)] (2a) with AgBF4 in acetonitrile and was used as a starting material in a ligand exchange reaction with the water soluble phosphine 1,3,5-triaza-7-phosphadamantane (PTA) to obtain the complex ReBr2(NO)(PTA)(3)]

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153 since deposited on 2011-02-24
Acq. date: 2025-11-13

Additional indexing

Creators (Authors)

  • Maccaroni, E
    affiliation.icon.alt
  • Dong, H
    affiliation.icon.alt
  • Blacque, O
    affiliation.icon.alt
  • Schmalle, H W
    affiliation.icon.alt
  • Frech, C M
    affiliation.icon.alt
  • Berke, H
    affiliation.icon.alt

Journal/Series Title

Journal/Series Title

Journal/Series Title

Volume

Volume

Volume
695

Number

Number

Number
4

Page range/Item number

Page range/Item number

Page range/Item number
487

Page end

Page end

Page end
494

Item Type

Item Type

Item Type
Journal Article

Dewey Decimal Classifikation

Dewey Decimal Classifikation

Dewey Decimal Classifikation

Language

Language

Language
English

Publication date

Publication date

Publication date
2010

Date available

Date available

Date available
2011-02-24

Publisher

Publisher

Publisher

ISSN or e-ISSN

ISSN or e-ISSN

ISSN or e-ISSN
0022-328X

OA Status

OA Status

OA Status
Closed

Other Identification Number

Other Identification Number

Other Identification Number
ISI:000274285200002

Metrics

Views

153 since deposited on 2011-02-24
Acq. date: 2025-11-13

Citations

Citation copied

Maccaroni, E., Dong, H., Blacque, O., Schmalle, H. W., Frech, C. M., & Berke, H. (2010). Water soluble phosphine rhenium complexes. Journal of Organometallic Chemistry, 695(4), 487–494. https://doi.org/10.1016/j.jorganchem.2009.11.031

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