Publication: Water soluble phosphine rhenium complexes
Water soluble phosphine rhenium complexes
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Maccaroni, E., Dong, H., Blacque, O., Schmalle, H. W., Frech, C. M., & Berke, H. (2010). Water soluble phosphine rhenium complexes. Journal of Organometallic Chemistry, 695(4), 487–494. https://doi.org/10.1016/j.jorganchem.2009.11.031
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Reduction of NMe4](2)ReBr5(NO)] (1) with zinc in acetonitrile leads to the known trisacetonitrile compound ReBr2(CH3CN)(3)(NO)] (2). Attempts to turn 2 into a dihydrogen or a hydride complex applying direct reaction with H-2 or with H-2 and a base were unsuccessful. Complex 2 could be transformed into ReBr(BF4)mer(CH3CN)(3)(NO)] (2a) with AgBF4 in acetonitrile and was used as a starting material in a ligand exchange reaction with the water soluble phosphine 1,3,5-triaza-7-phosphadamantane (PTA) to obtain the complex ReBr2(NO)(PTA)(3)]
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Maccaroni, E., Dong, H., Blacque, O., Schmalle, H. W., Frech, C. M., & Berke, H. (2010). Water soluble phosphine rhenium complexes. Journal of Organometallic Chemistry, 695(4), 487–494. https://doi.org/10.1016/j.jorganchem.2009.11.031