Publication: Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers
Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers
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Palomo, C., Oiarbide, M., García, J. M., Bañuelos, P., Odriozola, J. M., Razkin, J., & Linden, A. (2008). Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers. Organic Letters, 10(13), 2637–2640. https://doi.org/10.1021/ol800564d
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A camphor-based alpha'-hydroxy enone reagent acts as a chiral acrylate equivalent in copper-catalyzed Michael reactions of beta-keto esters and affords products that possess all-carbon quaternary stereocenters of high enantiomeric purity.
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- Palomo, C
- Oiarbide, M
- Odriozola, J M
- Razkin, J
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Palomo, C., Oiarbide, M., García, J. M., Bañuelos, P., Odriozola, J. M., Razkin, J., & Linden, A. (2008). Catalytic Michael reactions of ketoesters with a camphor-derived acrylate equivalent: stereoselective access to all-carbon quaternary centers. Organic Letters, 10(13), 2637–2640. https://doi.org/10.1021/ol800564d
