Publication: 4,4-Disubstituierte Imidazol-Derivate aus der Umsetzung von 3-Amino-2H-azirinen mit Salicylamid
4,4-Disubstituierte Imidazol-Derivate aus der Umsetzung von 3-Amino-2H-azirinen mit Salicylamid
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Magirius, F., Linden, A., & Heimgartner, H. (1994). 4,4-Disubstituierte Imidazol-Derivate aus der Umsetzung von 3-Amino-2H-azirinen mit Salicylamid. Helvetica Chimica Acta, 77(2), 453–462. https://doi.org/10.1002/hlca.19940770206
Abstract
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4,4-Disubstituted Imidazole Derivatives from the Reaction of 3-Amino-2H-azirines with Salicylamide Reaction of 3-amino-2H-azirines 1a-c with salicylamide (7) in MeCN leads to imidazoles 10 and 11 in different rates, depending on the conditions. In the case of 1a and 1b, 11a and 11b, respectively, have been obtained as the main product at 50°; in reactions at 80°, 10a and 10b are the favored products (Tables 1and 2). 2,2-Dimethyl-3-(N-methyl-N-phenylamino)-2H-azirine (1c) reacts with 7 in MeCN mainly to 2-(2-hydroxyphenyl)-5,5-dimethyl
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- Magirius, Florian
- Heimgartner, Heinz
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Magirius, F., Linden, A., & Heimgartner, H. (1994). 4,4-Disubstituierte Imidazol-Derivate aus der Umsetzung von 3-Amino-2H-azirinen mit Salicylamid. Helvetica Chimica Acta, 77(2), 453–462. https://doi.org/10.1002/hlca.19940770206
