Publication: K$^3$‐(N^C^C)Gold(III) Carboxylates: Evidence for Decarbonylation Processes
K$^3$‐(N^C^C)Gold(III) Carboxylates: Evidence for Decarbonylation Processes
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Beucher, H., Merino, E., Genoux, A., Fox, T., & Nevado, C. (2019). K$^3$‐(N^C^C)Gold(III) Carboxylates: Evidence for Decarbonylation Processes. Angewandte Chemie Internationale Edition, 131(27), 9162–9165. https://doi.org/10.1002/ange.201903098
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Abstract
Gold(III) carboxylate species, stabilized by a κ3‐(N^C^C) ligand template, are presented herein. A η1‐AuIII‐C(O)‐OH species has been characterized under cryogenic conditions as a result of the nucleophilic attack of an ammonium hydroxide onto a dinuclear μ‐CO2‐κ3‐(N^C^C)AuIII precursor. Thermal decomposition for these species proceeds by an unusual decarbonylation process, in contrast to typical decarboxylation pathways observed in related metallocarboxylic acids.
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- Beucher, Hélène
- Merino, Estíbaliz
- Genoux, Alexandre
- Fox, Thomas
- Nevado, Cristina
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Beucher, H., Merino, E., Genoux, A., Fox, T., & Nevado, C. (2019). K$^3$‐(N^C^C)Gold(III) Carboxylates: Evidence for Decarbonylation Processes. Angewandte Chemie Internationale Edition, 131(27), 9162–9165. https://doi.org/10.1002/ange.201903098
