Publication: Ammonia borane as a metal free reductant for ketones and aldehydes: a mechanistic study
Date
Date
Date
2011
Journal Article
Published version
Abstract
Abstract
Abstract
Without a catalyst ketones and aldehydes were reacted in THF with ammonia borane (AB) to proceed hydroboration forming alkyl borates. Mechanistic studies revealed that dissociation of ammonia from AB occurred before the hydroboration step. When methanol was used as the solvent, metal free methanolysis of AB would take place with the ketone/aldehyde being directly hydrogenated by the MeOH center dot BH(3) complex. (C) 2011 Elsevier Ltd. All rights reserved.
Metrics
Views
236 since deposited on 2012-03-05
Acq. date: 2025-11-14
Additional indexing
Creators (Authors)
- Yang, X
- Fox, T
- Berke, H
Volume
Volume
Volume
67
Number
Number
Number
37
Page range/Item number
Page range/Item number
Page range/Item number
7121
Page end
Page end
Page end
7127
Item Type
Item Type
Item Type
Journal Article
In collections
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Dewey Decimal Classifikation
Language
Language
Language
English
Publication date
Publication date
Publication date
2011-09
Date available
Date available
Date available
2012-03-05
ISSN or e-ISSN
ISSN or e-ISSN
ISSN or e-ISSN
0040-4020
OA Status
OA Status
OA Status
Closed
Publisher DOI
Other Identification Number
Other Identification Number
Other Identification Number
ISI:000294574400016
Metrics
Views
236 since deposited on 2012-03-05
Acq. date: 2025-11-14
Closed
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