Publication: Coexistence of Racemic and Homochiral Two-Dimensional Lattices Formed by a Prochiral Molecule: Dicarboxystilbene on Cu(110)
Coexistence of Racemic and Homochiral Two-Dimensional Lattices Formed by a Prochiral Molecule: Dicarboxystilbene on Cu(110)
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Cortés, R., Mascaraque, A., Schmidt Weber, P., Dil, H., Kampen, T. U., & Horn, K. (2008). Coexistence of Racemic and Homochiral Two-Dimensional Lattices Formed by a Prochiral Molecule: Dicarboxystilbene on Cu(110). Nano Letters, 8, 4162–4167. https://doi.org/10.1021/nl801592c
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Abstract
Dicarboxystilbene, a molecule that becomes chiral in the adsorbed state through the loss of its improper axis of rotation, forms long-range "handed" structures when adsorbed on Cu(110) as revealed by scanning tunnelling microscopy. We show that these structures are created from chiral "adsorption complex" building blocks, giving rise to a complete set of racemic and enantiomerically pure structural assemblies. We interpret the formation of these structures in terms of a balance between hydrogen bond mediated intermolecular interaction
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- Cortés, R
- Mascaraque, A
- Schmidt Weber, P
- Dil, H
- Kampen, T U
- Horn, K
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Cortés, R., Mascaraque, A., Schmidt Weber, P., Dil, H., Kampen, T. U., & Horn, K. (2008). Coexistence of Racemic and Homochiral Two-Dimensional Lattices Formed by a Prochiral Molecule: Dicarboxystilbene on Cu(110). Nano Letters, 8, 4162–4167. https://doi.org/10.1021/nl801592c
