Publication: Cross-Coupling Reactions of Monosubstituted Tetrazines
Cross-Coupling Reactions of Monosubstituted Tetrazines
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Hoff, L. V., Schnell, S. D., Tomio, A., Linden, A., & Gademann, K. (2021). Cross-Coupling Reactions of Monosubstituted Tetrazines. Organic Letters, 23(15), 5689–5692. https://doi.org/10.1021/acs.orglett.1c01813
Abstract
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Abstract
A Ag-mediated Pd-catalyzed cross-coupling method for 3-bromo-1,2,4,5-tetrazine with boronic acids is presented. Electronic modification of the 1,1′-bis(diphenylphosphine)ferrocene (dppf) ligand was found to be crucial for good turnover. Using this fast method, a variety of alkyl-, heteroatom-, and halide-substituted aryl- and heteroaryl-tetrazines were prepared (29 examples, up to 87% yield).
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- Hoff, Lukas V
- Schnell, Simon D
- Tomio, Andrea
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Hoff, L. V., Schnell, S. D., Tomio, A., Linden, A., & Gademann, K. (2021). Cross-Coupling Reactions of Monosubstituted Tetrazines. Organic Letters, 23(15), 5689–5692. https://doi.org/10.1021/acs.orglett.1c01813
