Publication: Synthesis of a Derivative of the Peptaibol-Antibiotic Trichovirin I 1B by means of the 'Azirine/Oxazolone Method'
Synthesis of a Derivative of the Peptaibol-Antibiotic Trichovirin I 1B by means of the 'Azirine/Oxazolone Method'
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Luykx, R. T. N., Linden, A., & Heimgartner, H. (2003). Synthesis of a Derivative of the Peptaibol-Antibiotic Trichovirin I 1B by means of the “Azirine/Oxazolone Method.” Helvetica Chimica Acta, 86(12), 4093–4111. https://doi.org/10.1002/hlca.200390339
Abstract
Abstract
Abstract
According to the earlier published synthesis of the C-terminal nonapeptide of Trichovirin I 1B, Z-Ser(tBu)-Val-Aib-Pro-Aib-Leu-Aib-Pro-Leuol (5), the complete tetradecapeptide Z-Aib-Asn(Trt)-Leu-Aib-Pro-Ser(t-Bu)-Val-Aib-Pro-Aib-Leu-Aib-Pro-Leuol (11b), a protected Trichovirin I 1B, has now been prepared by means of the 'azirine/oxazolone method'. With the exception of the N-terminal Aib(1), all Aib residues were introduced by the coupling of the corresponding amino or peptide acids with 2,2-dimethyl-2H-azirine-3-(N- methyl-N-phenylam
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- Luykx, Roeland T N
- Heimgartner, Heinz
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Luykx, R. T. N., Linden, A., & Heimgartner, H. (2003). Synthesis of a Derivative of the Peptaibol-Antibiotic Trichovirin I 1B by means of the “Azirine/Oxazolone Method.” Helvetica Chimica Acta, 86(12), 4093–4111. https://doi.org/10.1002/hlca.200390339
