Publication: Total synthesis and structural revision of aeruginosin KT608A
Total synthesis and structural revision of aeruginosin KT608A
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Scherer, M., & Gademann, K. (2017). Total synthesis and structural revision of aeruginosin KT608A. Organic Letters, 19(14), 3915–3918. https://doi.org/10.1021/acs.orglett.7b01822
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The synthesis of the presumed structure of aeruginosin KT608A was accomplished for the first time. The unusual D-diepi-Choi core was prepared from tyrosine via C-H activation and heterogeneous hydrogenation. Due to differences in the spectral data of synthetic and natural samples, a revised structure featuring L-diepi-Choi was proposed, which was synthesized and confirmed to be identical. Based on these findings, revised structures for six additional aeruginosins (KT608B, KT650, GH553, DA495A, DA511 and KB676) are presented.
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- Scherer, Manuel
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Scherer, M., & Gademann, K. (2017). Total synthesis and structural revision of aeruginosin KT608A. Organic Letters, 19(14), 3915–3918. https://doi.org/10.1021/acs.orglett.7b01822
