Publication: Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes
Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes
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Du, X., Cheng-Sánchez, I., & Nevado, C. (2023). Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes. Journal of the American Chemical Society, 145, 12532–12540. https://doi.org/10.1021/jacs.3c00744
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An asymmetricthree-componentcarbosulfonylationof alkenesis presentedhere. The reaction,involvingthesimultaneousformationof a C−C and a C−S bond acrosstheπ-system,uses a dual nickel/photoredoxcatalyticsystemto producebothβ-aryl andβ-alkenylsulfonesin high yields and with excellentlevels of stereocontrol(up to 99:1 er). This protocolexhibitsabroadsubstratescope and excellentfunctionalgrouptoleranceand its syntheticpotentialhas been demonstratedby successfulapplicationstowardpharmacologicallyrelevantmolecules.A broadarray of controle
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- Du, Xiaoyong
- Cheng-Sánchez, Iván
- Nevado, Cristina
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Du, X., Cheng-Sánchez, I., & Nevado, C. (2023). Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes. Journal of the American Chemical Society, 145, 12532–12540. https://doi.org/10.1021/jacs.3c00744
