Publication: Experimental and computational studies on pseudotetrahedral nickel(ii)-(S or R)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal
Experimental and computational studies on pseudotetrahedral nickel(ii)-(S or R)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal
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Saadati, A., Amiri Rudbari, H., Aryaeifar, M., Blacque, O., Correia, I., Islam, M. K., Woschko, D., Haj Hassani Sohi, T., Janiak, C., & Enamullah, M. (2023). Experimental and computational studies on pseudotetrahedral nickel(ii)-(S or R)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal. CrystEngComm, 25, 365–377. https://doi.org/10.1039/d2ce01311h
Abstract
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In this study, three pairs of pseudotetrahedral C2-symmetrical bis[(S or R)-N-1-(phenyl)ethyl-(2,4-X1,X2-salicylaldiminato-κ2N,O)]-Δ/Λ-nickel(II), Δ/Λ-NiSL1–3 or Λ/Δ-NiRL1–3 (X1, X2 = Cl, Cl; Br, Br; Cl, Br) with Δ- or Λ-chirality induction at-metal were synthesized, respectively. X-ray molecular structures showed the formation of a N2O2-chromophore around nickel(II) from two molecules of Schiff bases in a pseudotetrahedral geometry. The structural analysis further suggested the isolation of opposite configured Δ-Ni and Λ-Ni diastereo
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- Saadati, Arezoo
- Amiri Rudbari, Hadi
- Aryaeifar, Mahnaz
- Correia, Isabel
- Islam, Mohammad Khairul
- Woschko, Dennis
- Haj Hassani Sohi, Takin
- Janiak, Christoph
- Enamullah, Mohammed
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Saadati, A., Amiri Rudbari, H., Aryaeifar, M., Blacque, O., Correia, I., Islam, M. K., Woschko, D., Haj Hassani Sohi, T., Janiak, C., & Enamullah, M. (2023). Experimental and computational studies on pseudotetrahedral nickel(ii)-(S or R)-dihalogen-salicylaldiminates with Δ- or Λ-chirality induction at-metal. CrystEngComm, 25, 365–377. https://doi.org/10.1039/d2ce01311h
