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Orahovats, Alexander; Jackson, Barry; Heimgartner, Heinz; Schmid, Hans (1973). Photoinduzierte Cycloadditionen von 3-Benzyl-2H-azirin. Helvetica Chimica Acta, 56(6):2007-2011.
Irradiation of 2-azido-3-phenyl-propene (5) in pentane or benzene solution with a high pressure lamp (Pyrex filter) yields 3-benzyl-2H-azirin (6), which on further irradiation behind quartz or vycor in the presence of trifluoroacetic acid methyl ester or carbon dioxide yields 4-benzyl-5-methoxy-5-trifluoromethyl-3-oxazoline (8) and 4-benzyl-3-oxazolin-5-one (9), respectively (scheme 2). A small amount of 3-phenylacetonitrile is also formed.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Life Sciences > Biochemistry Life Sciences > Drug Discovery Physical Sciences > Physical and Theoretical Chemistry Physical Sciences > Organic Chemistry Physical Sciences > Inorganic Chemistry |
| Uncontrolled Keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Biochemistry, Drug Discovery, Catalysis |
| Language: | German |
| Date: | 1973 |
| Deposited On: | 09 Dec 2014 15:40 |
| Last Modified: | 12 Mar 2025 02:37 |
| Publisher: | Wiley-Blackwell Publishing, Inc. |
| ISSN: | 0018-019X |
| Funders: | Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/hlca.19730560621 |
| Project Information: |
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Orahovats, Alexander