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Braband, Henrik; Benz, Michael; Tooyama, Yuji; Alberto, Roger (2014). Activation of [$^{99(m)}$TcO$_4$]− by phosphonium cations. Chemical Communications, 50(31):4126-4129.
Phosphonium salts in solution or bound to solid phase supports interact with the robust [$^{99(m)}$TcO$_4$]− anion in neutral water. This activated form of [$^{99(m)}$TcO$_4$]− represents a source for complexes with the fac-{$^{99(m)}$Tc$^{VII}$O$_3$}+ core, which can be synthesized in high yields and purity.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Language: | English |
| Date: | 2014 |
| Deposited On: | 20 Feb 2015 09:53 |
| Last Modified: | 12 Mar 2025 02:40 |
| Publisher: | RSC Publishing |
| ISSN: | 1359-7345 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1039/c4cc00718b |
Braband, Henrik