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Bachmann, Cyril; Probst, Benjamin; Guttentag, Miguel; Alberto, Roger (2014). Ascorbate as an electron relay between an irreversible electron donor and Ru(ii) or Re(i) photosensitizers. Chemical Communications, 50(51):6737-6739.
Ascorbate acts as a reversible electron shuttle between tris(2-carboxyethyl) phosphine (TCEP) and ReI or RuII photosensitizers. Oxidized ascorbate is recycled up to 50 times by the TCEP → TCEP[double bond, length as m-dash]O redox process which enables 30 000 TONs per WRC in photocatalytic hydrogen production, thus exceeding the performance with pure ascorbate by far.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Language: | English |
| Date: | 2014 |
| Deposited On: | 20 Feb 2015 10:00 |
| Last Modified: | 12 Mar 2025 02:40 |
| Publisher: | RSC Publishing |
| ISSN: | 1359-7345 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1039/c4cc01500b |
Bachmann, Cyril