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Mlostoń, Grzegorz; Urbaniak, Katarzyna; Pawlak, Aneta; Heimgartner, Heinz (2016). New applications of hetaryl thioketones for the synthesis of hetaryl-substituted ethenes via ‘two-fold extrusion reaction‘. Heterocycles, 93(1):127-139.
A series of aryl/hetaryl thioketones was applied for the reactions with aryl/hetaryldiazomethanes yielding, after elimination of N2, the corresponding thiiranes. The relatively unstable dihetaryldiazomethanes were generated in situ from the corresponding hydrazones by oxidation with DMSO. The obtained thiiranes were converted into tetraaryl/hetaryl-substituted ethenes in good yields by desulfurization performed with tris(diethylamino)phosphine ((Et2N)3P).
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Analytical Chemistry
Life Sciences > Pharmacology Physical Sciences > Organic Chemistry |
| Language: | English |
| Date: | 2016 |
| Deposited On: | 15 Oct 2015 14:45 |
| Last Modified: | 13 Mar 2025 02:39 |
| Publisher: | Elsevier |
| ISSN: | 0385-5414 |
| Funders: | National Science Center (Cracow, Poland) |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.3987/COM-15-S(T)8 |
| Related URLs: | https://www.heterocycles.jp/newlibrary/libraries/prepress/special |
Mlostoń, Grzegorz