Ohno, Koichi; Satoh, Hiroko; Iwamoto, Takeaki (2015). A prism carbon molecule C$_20$. Chemistry Letters, 44(5):712-714.
A new carbon family with a prism structure has been found by quantum chemical calculations. The prism-$C_20$ has a $D_10h$ structure with double-layered decagonal rings connected each other by ten vertical CC bonds. The CC bond lengths are 0.144 nm on the decagonal rings and 0.148 nm on the side faces. The diameter of the ring is 0.465 nm. The $prism-C_20$ is expected to be stable, since the lowest energy barrier from it was estimated to be 158.0 kJ mol$^−1$.
A new carbon family with a prism structure has been found by quantum chemical calculations. The prism-$C_20$ has a $D_10h$ structure with double-layered decagonal rings connected each other by ten vertical CC bonds. The CC bond lengths are 0.144 nm on the decagonal rings and 0.148 nm on the side faces. The diameter of the ring is 0.465 nm. The $prism-C_20$ is expected to be stable, since the lowest energy barrier from it was estimated to be 158.0 kJ mol$^−1$.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > General Chemistry |
| Language: | English |
| Date: | 2015 |
| Deposited On: | 21 Dec 2015 15:22 |
| Last Modified: | 26 Mar 2020 00:21 |
| Publisher: | Chemical Society of Japan |
| ISSN: | 0366-7022 |
| OA Status: | Hybrid |
| Publisher DOI: | https://doi.org/10.1246/cl.150120 |
Ohno, Koichi