Oesch, David; Luedtke, Nathan W (2015). Fluorescent chemosensors of carbohydrate triols exhibiting TICT emissions. Journal of the Chemical Society. Chemical Communications, 2015(51):12641-12644.
4-4′-Disubstituted biphenyl boronic acids (BBAs) are push–pull fluorophores with “turn-on” fluorescence properties. Upon carbohydrate triol binding, BBA boronate esters can participate in photon-induced electron transfer, giving a twisted intramolecular charge transfer (TICT) complex. The resulting TICT emissions distinguish between carbohydrates that bind to boron as a diol versus triol unit, thereby revealing stereochemical information about the carbohydrate.
4-4′-Disubstituted biphenyl boronic acids (BBAs) are push–pull fluorophores with “turn-on” fluorescence properties. Upon carbohydrate triol binding, BBA boronate esters can participate in photon-induced electron transfer, giving a twisted intramolecular charge transfer (TICT) complex. The resulting TICT emissions distinguish between carbohydrates that bind to boron as a diol versus triol unit, thereby revealing stereochemical information about the carbohydrate.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Language: | English |
| Date: | 29 June 2015 |
| Deposited On: | 21 Dec 2015 14:05 |
| Last Modified: | 16 Nov 2022 08:15 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 0022-4936 |
| Additional Information: | Persons who receive the PDF must not make it further available or distribute it. |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1039/C5CC03857J |
Oesch, David