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Malashikhin, S A; Linden, Anthony; Heimgartner, H; Rodina, L L; Nikolaev, V A (2008). Synthesis and structures of two isomeric 4-diazo-2,3,4,5-tetrahydrofuran-3-ones. Helvetica Chimica Acta, 91(9):1662-1668.
The two regioisomeric 4-diazo-2,3,4,5-tetrahydrofuran-3-ones 6 and 7 were prepared via the common intermediate 2,3,4,5-tetrahydro-2,2-dimethyl-5,5-diphenylfuran-3-one (8). Diazo transfer with 2,4,6-triisopropylbenzenesulfonyl azide yielded 6, whereas 7 was obtained via oxidation of the monohydrazone 12, which was prepared selectively from tetrahydrofuran-3,4-dione 11. The crystal structures of 6 and 7 have been established by X-ray crystallography.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Life Sciences > Biochemistry Life Sciences > Drug Discovery Physical Sciences > Physical and Theoretical Chemistry Physical Sciences > Organic Chemistry Physical Sciences > Inorganic Chemistry |
| Uncontrolled Keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry, Organic Chemistry, Biochemistry, Drug Discovery, Catalysis |
| Language: | English |
| Date: | September 2008 |
| Deposited On: | 06 Feb 2009 11:16 |
| Last Modified: | 02 Mar 2025 02:38 |
| Publisher: | Verlag Helvetica Chimica Acta |
| ISSN: | 0018-019X |
| Funders: | F. Hoffmann-La Roche AG, Basel |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/hlca.200890182 |
Malashikhin, S A