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Isoselenocyanates as building blocks for Selenium-containing heterocycles


Heimgartner, H; Zhou, Y; Atanassov, P K; Sommen, G L (2008). Isoselenocyanates as building blocks for Selenium-containing heterocycles. Phosphorus, Sulfur and Silicon and the Related Elements, 183(4):840-855.

Abstract

Isoselenocyanates are conveniently accessible from elemental selenium in safe and efficient reactions. They can be used either as reactive intermediates or as relatively stable and storable starting materials for the preparation of selenaheterocycles or heterocyclic selones. In most cases, the reactions are initiated by a nucleophilic attack onto the isoselenocyanate, followed by a cyclization via the Se- or the N-atom. Alternatively, the intermediate adduct of the nucleophile and the isoselenocyanate can undergo a second nucleophilic addition with a third compound and subsequent cyclization.

Abstract

Isoselenocyanates are conveniently accessible from elemental selenium in safe and efficient reactions. They can be used either as reactive intermediates or as relatively stable and storable starting materials for the preparation of selenaheterocycles or heterocyclic selones. In most cases, the reactions are initiated by a nucleophilic attack onto the isoselenocyanate, followed by a cyclization via the Se- or the N-atom. Alternatively, the intermediate adduct of the nucleophile and the isoselenocyanate can undergo a second nucleophilic addition with a third compound and subsequent cyclization.

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Additional indexing

Item Type:Journal Article, refereed, further contribution
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:2008
Deposited On:06 Feb 2009 09:22
Last Modified:18 Feb 2018 10:45
Publisher:Taylor & Francis
ISSN:1026-7719
OA Status:Closed
Publisher DOI:https://doi.org/10.1080/10426500801898135

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