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Enantioselective synthesis of di-, tri-, and tetrasubstituted allenylsilanes


Guintchin, Boris K; Bienz, Stefan (2004). Enantioselective synthesis of di-, tri-, and tetrasubstituted allenylsilanes. Organometallics, 23(21):4944-4951.

Abstract

A number of differently substituted allenylsilanes were prepared by cuprate substitution of α-acetoxy- and α-mesyloxypropargylic silanes. The reactions were shown to proceed stereospecifically by the attack of the nucleophile anti to the leaving group.

Abstract

A number of differently substituted allenylsilanes were prepared by cuprate substitution of α-acetoxy- and α-mesyloxypropargylic silanes. The reactions were shown to proceed stereospecifically by the attack of the nucleophile anti to the leaving group.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Organic Chemistry
Physical Sciences > Inorganic Chemistry
Language:English
Date:16 September 2004
Deposited On:23 Aug 2017 16:01
Last Modified:31 Jul 2020 01:14
Publisher:American Chemical Society (ACS)
ISSN:0276-7333
OA Status:Closed
Publisher DOI:https://doi.org/10.1021/om049505e

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