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The first gold(III) formate: evidence for β-hydride elimination


Kumar, Roopender; Krieger, Jean-Philippe; Gómez-Bengoa, Enrique; Fox, Thomas; Linden, Anthony; Nevado, Cristina (2017). The first gold(III) formate: evidence for β-hydride elimination. Angewandte Chemie Internationale Edition, 56(42):12862-12865.

Abstract

The first stable gold(III) formate and experimental evidence for its β-hydride elimination are described. A catalytic dehydrogenation of formic acid together with mechanistic studies shed light on potential pathways operating in fundamental gold-catalyzed transformations.

Abstract

The first stable gold(III) formate and experimental evidence for its β-hydride elimination are described. A catalytic dehydrogenation of formic acid together with mechanistic studies shed light on potential pathways operating in fundamental gold-catalyzed transformations.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Uncontrolled Keywords:General Chemistry, Catalysis
Language:English
Date:2017
Deposited On:18 Jan 2018 17:17
Last Modified:19 Aug 2018 12:21
Publisher:Wiley-VCH Verlag
ISSN:1433-7851
OA Status:Closed
Publisher DOI:https://doi.org/10.1002/anie.201705557
PubMed ID:28902956
Project Information:
  • : FunderFP7
  • : Grant ID307948
  • : Project TitleNIGOCAT - Nature-Inspired Gold Catalytic Tools

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