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Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks


Zhang, Kang; Shen, Yunjun; Liu, Jiyong; Spingler, Bernhard; Duttwyler, Simon (2018). Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks. Chemical Communications, 54(14):1698-1701.

Abstract

The crystal structure of the deprotonated monocarba-closododecaborate [12-CN-CB11H11]- is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C–[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

Abstract

The crystal structure of the deprotonated monocarba-closododecaborate [12-CN-CB11H11]- is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C–[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Language:English
Date:1 January 2018
Deposited On:03 Oct 2018 14:20
Last Modified:04 Oct 2018 07:32
Publisher:Royal Society of Chemistry
ISSN:1359-7345
OA Status:Closed
Publisher DOI:https://doi.org/10.1039/c7cc07724f

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