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Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Zhang, Kang; Shen, Yunjun; Liu, Jiyong; Spingler, Bernhard; Duttwyler, Simon (2018). Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks. Chemical Communications, 54(14):1698-1701.

Abstract

The crystal structure of the deprotonated monocarba-closododecaborate [12-CN-CB11H11]- is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C–[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials
Physical Sciences > Ceramics and Composites
Physical Sciences > General Chemistry
Physical Sciences > Surfaces, Coatings and Films
Physical Sciences > Metals and Alloys
Physical Sciences > Materials Chemistry
Language:English
Date:1 January 2018
Deposited On:03 Oct 2018 14:20
Last Modified:19 Jan 2025 02:40
Publisher:Royal Society of Chemistry
ISSN:1359-7345
OA Status:Closed
Publisher DOI:https://doi.org/10.1039/c7cc07724f
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