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Huang, Bin; Liffert, Raphael; Linden, Anthony; Gademann, Karl (2019). Metal Free Regioselective Chloroazidation of Internal Alkynes. Chemistry - A European Journal, 25(4):981-984.
A metal‐free, room temperature protocol for the regioselective chloroazidation of internal alkynes is disclosed. The reactions of internal alkynes with trimethylsilyl azide (TMS‐N3) in the presence of 1,3‐dichloro‐5,5‐dimethylhydantoin (DCDMH) afforded the corresponding chloroazidoalkenes in good yields. This reaction displays good functional group tolerance and is operationally simple.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Organic Chemistry |
| Uncontrolled Keywords: | General Chemistry |
| Language: | English |
| Date: | 18 January 2019 |
| Deposited On: | 22 Nov 2018 06:43 |
| Last Modified: | 27 Aug 2024 03:32 |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 0947-6539 |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.1002/chem.201805320 |
Huang, Bin