Header

UZH-Logo

Maintenance Infos

Crystal structure of a new 2,6-bis­­(imino)­pyridine derivative: (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­­[N-(4-chloro­phen­yl)ethan-1-imine]


Rajesh, Rajagopal; Sella, E S; Blacque, Olivier; Rajesh, Kunjanpillai (2019). Crystal structure of a new 2,6-bis­­(imino)­pyridine derivative: (1E,1′E)-1,1′-(pyridine-2,6-di­yl)bis­­[N-(4-chloro­phen­yl)ethan-1-imine]. Acta Crystallographica. Section E: Structure Reports Online, 75:115-118.

Abstract

The asymmetric unit of the title compound, C21H17Cl2N3, contains two crystallographically independent mol­ecules (A and B). Both mol­ecules have E configurations for both imine double bonds with regard to the aryl and pyridine groups. The conformations of the two mol­ecules differ with the 4-chloro­phenyl rings being inclined to the central pyridine ring by 77.64 (6) and 86.18 (6)° in mol­ecule A, and 80.02 (5) and 43.41 (6)° in mol­ecule B. In the crystal, mol­ecules are linked by a number of C—H⋯π inter­actions, forming layers parallel to the bc plane.

Abstract

The asymmetric unit of the title compound, C21H17Cl2N3, contains two crystallographically independent mol­ecules (A and B). Both mol­ecules have E configurations for both imine double bonds with regard to the aryl and pyridine groups. The conformations of the two mol­ecules differ with the 4-chloro­phenyl rings being inclined to the central pyridine ring by 77.64 (6) and 86.18 (6)° in mol­ecule A, and 80.02 (5) and 43.41 (6)° in mol­ecule B. In the crystal, mol­ecules are linked by a number of C—H⋯π inter­actions, forming layers parallel to the bc plane.

Statistics

Citations

Dimensions.ai Metrics
1 citation in Web of Science®
1 citation in Scopus®
Google Scholar™

Altmetrics

Downloads

34 downloads since deposited on 30 Jan 2019
5 downloads since 12 months
Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > General Chemistry
Physical Sciences > General Materials Science
Physical Sciences > Condensed Matter Physics
Language:English
Date:February 2019
Deposited On:30 Jan 2019 17:29
Last Modified:01 Dec 2023 08:08
Publisher:International Union of Crystallography
ISSN:1600-5368
OA Status:Gold
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.1107/S2056989018017966
Official URL:http://journals.iucr.org/e/issues/2019/02/00/su5463/index.html
  • Content: Published Version
  • Licence: Creative Commons: Attribution 4.0 International (CC BY 4.0)