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Visible Light Mediated, Redox Neutral Remote 1,6-Difunctionalizations of Alkenes


Shu, Wei; Merino, Estíbaliz; Nevado, Cristina (2018). Visible Light Mediated, Redox Neutral Remote 1,6-Difunctionalizations of Alkenes. ACS Catalysis, 8(7):6401-6406.

Abstract

A photoinduced cascade strategy is presented here for the remote functionalization of alkenes under redox neutral conditions. A broad portfolio of alkyl groups has been added to double bonds to produce, upon 1,5-HAT, remote C-centered radicals which can be harvested in the presence of O- or C-nucleophiles to efficiently form Csp(3)-O and Csp(3)-Csp(2) bonds at room temperature.

Abstract

A photoinduced cascade strategy is presented here for the remote functionalization of alkenes under redox neutral conditions. A broad portfolio of alkyl groups has been added to double bonds to produce, upon 1,5-HAT, remote C-centered radicals which can be harvested in the presence of O- or C-nucleophiles to efficiently form Csp(3)-O and Csp(3)-Csp(2) bonds at room temperature.

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Additional indexing

Item Type:Journal Article, not_refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > General Chemistry
Language:English
Date:6 July 2018
Deposited On:07 Mar 2019 07:33
Last Modified:29 Jul 2020 10:06
Publisher:American Chemical Society (ACS)
ISSN:2155-5435
OA Status:Closed
Publisher DOI:https://doi.org/10.1021/acscatal.8b00707
Project Information:
  • : FunderSNSF
  • : Grant ID200020_146853
  • : Project TitleNovel Synthetic Methods based on Gold Catalyzed Reactions
  • : FunderFP7
  • : Grant ID307948
  • : Project TitleNIGOCAT - Nature-Inspired Gold Catalytic Tools

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