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Shu, Wei; Merino, Estíbaliz; Nevado, Cristina (2018). Visible Light Mediated, Redox Neutral Remote 1,6-Difunctionalizations of Alkenes. ACS Catalysis, 8(7):6401-6406.
A photoinduced cascade strategy is presented here for the remote functionalization of alkenes under redox neutral conditions. A broad portfolio of alkyl groups has been added to double bonds to produce, upon 1,5-HAT, remote C-centered radicals which can be harvested in the presence of O- or C-nucleophiles to efficiently form Csp(3)-O and Csp(3)-Csp(2) bonds at room temperature.
| Item Type: | Journal Article, not_refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry |
| Language: | English |
| Date: | 6 July 2018 |
| Deposited On: | 07 Mar 2019 07:33 |
| Last Modified: | 30 Aug 2024 03:37 |
| Publisher: | American Chemical Society (ACS) |
| ISSN: | 2155-5435 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1021/acscatal.8b00707 |
| Project Information: |
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Shu, Wei