Kurz, P; Spingler, B; Fox, T; Alberto, R (2004). [TcI(CN)3(CO)3]2- and [ReI(CN)3(CO)3]2- :case studies for the binding properties of CN- and CO. Inorganic Chemistry, 43(13):3789-3791.
The cyano carbonyl complexes [(99)Tc(CN)(3)(CO)(3)]2- and [Re(CN)(3)(CO)(3)]2- were synthesized and fully characterized. These complexes are additional members of the well-known d(6) transition metal complex series [M(CN)(3)(CO)(3)](n-). The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.
The cyano carbonyl complexes [(99)Tc(CN)(3)(CO)(3)]2- and [Re(CN)(3)(CO)(3)]2- were synthesized and fully characterized. These complexes are additional members of the well-known d(6) transition metal complex series [M(CN)(3)(CO)(3)](n-). The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.
| Item Type: | Journal Article, refereed |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Inorganic Chemistry |
| Language: | English |
| Date: | 28 June 2004 |
| Deposited On: | 11 Feb 2008 12:25 |
| Last Modified: | 23 Jan 2022 08:56 |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1021/ic049774x |
| PubMed ID: | 15206855 |
Kurz, P