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Venkatesan, K; Fernández, F J; Blacque, Olivier; Fox, T; Alfonso, M; Schmalle, H W; Berke, Heinz (2003). A facile and novel route to unprecedented manganese C4 cumulenic complexes. Chemical Communications, 16:2006-2008.
The theoretically characterized (DFT) C4 cumulenic species Mn(C5H4R)(dmpe) [=C=C=C=C(SnPh3)2] was obtained by photolysis of the C(sp2)-Sn bond in the vinylidene complex Mn(C5H4R)(dmpe)[=C=C(SnPh3)-C[triple bond]CSnPh3], which in turn was prepared by a thermal reaction from MnC5H4R(dmpe)(C7H8) and Ph3Sn-C4-SnPh3.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Language: | English |
| Date: | 21 August 2003 |
| Deposited On: | 11 Feb 2008 12:25 |
| Last Modified: | 01 Mar 2025 02:37 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1039/b304882a |
| PubMed ID: | 12934885 |
Venkatesan, K