Halobismuth(III) salts with substituted aminopyridinium cations

Abstract

The crystal structures of six halobismuth(III) salts of variously substituted amino­pyridinium cations display discrete mononuclear [BiCl6]3− and dinuclear [Bi2X10]4− anions (X = Cl or Br), and polymeric cis-double-halo-bridged [BinX4n]n− anionic chains (X = Br or I). Bis(2-amino-3-ammonio­pyridinium) hexa­chlorido­bis­muth(III) chloride monohydrate, (C5H9N3)2[BiCl6]Cl·H2O, (1), contains discrete mononuclear [BiCl6]3− and chloride anions. Tetra­kis(2-amino-3-methyl­pyridinium) di-μ-chlorido-bis­[tetra­chlorido­bis­muth(III)], (C6H9N2)4[Bi2Cl10], (2), tetra­kis­(2-amino-3-methyl­pyridinium) di-μ-bromido-bis­[tetra­bro­mido­bis­muth(III)], (C6H9N2)4[Bi2Br10], (3), and bis­(4-amino-3-ammonio­pyri­din­ium) di-μ-chlorido-bis­[tetra­chlorido­bis­muth(III)] dihydrate, (C5H9N3)2[Bi2Cl10]·2H2O, (4), incorporate discrete [Bi2X10]4− anions (X = Cl or Br), while catena-poly[2,6-di­amino­pyridinium [[cis-di­iodido­bis­muth(III)]-di-μ-iodido]], {(C5H8N3)[BiI4]}n, (5), and catena-poly[2,6-di­amino­pyridinium [[cis-di­bromido­bis­muth(III)]-di-μ-bromido]], {(C5H7N2)[BiBr4]}n, (6), include [BinX4n]n− anionic chains (X = Br or I). Structures (2) and (3) are isostructural, while that of (5) is a pseudomerohedral twin. There is no discernible correlation between the type of anionic species obtained and the cation or halide ligand used. The BiIII centres always have a slightly distorted octa­hedral geometry and there is a correlation between the Bi—X bond lengths and the number of classic N—H...X hydrogen bonds that the X ligand accepts, with a greater number of inter­actions corresponding with slightly longer Bi—X distances. The supra­molecular networks formed by classic N—H...X hydrogen bonds include ladders, bilayers and three-dimensional frameworks.