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Beucher, Hélène; Merino, Estíbaliz; Genoux, Alexandre; Fox, Thomas; Nevado, Cristina (2019). K$^3$‐(N^C^C)Gold(III) Carboxylates: Evidence for Decarbonylation Processes. Angewandte Chemie Internationale Edition, 131(27):9162-9165.
Gold(III) carboxylate species, stabilized by a κ3‐(N^C^C) ligand template, are presented herein. A η1‐AuIII‐C(O)‐OH species has been characterized under cryogenic conditions as a result of the nucleophilic attack of an ammonium hydroxide onto a dinuclear μ‐CO2‐κ3‐(N^C^C)AuIII precursor. Thermal decomposition for these species proceeds by an unusual decarbonylation process, in contrast to typical decarboxylation pathways observed in related metallocarboxylic acids.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry |
| Uncontrolled Keywords: | General Chemistry, Catalysis |
| Language: | English |
| Date: | 1 July 2019 |
| Deposited On: | 29 Jul 2020 08:42 |
| Last Modified: | 22 Mar 2025 02:42 |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 1433-7851 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1002/ange.201903098 |
| Project Information: |
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Beucher, Hélène