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Haider, Victoria; Kreuzer, Viktoria; Tiffner, Maximilian; Spingler, Bernhard; Waser, Mario (2020). Ammonium salt-catalyzed ring-opening of aryl-aziridines with β-keto esters. European Journal of Organic Chemistry, 2020(32):5173-5177.
We herein report an ammonium salt-catalyzed protocol for the regioselective ring opening of aryl-aziridines with beta-keto esters. The reaction gives access to a variety of highly functionalized target molecules with two consecutive stereogenic
centers and can be rendered enantioselective (up to e.r. = 91:9) by using bifunctional chiral ammonium salt catalysts.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Physical and Theoretical Chemistry
Physical Sciences > Organic Chemistry |
| Uncontrolled Keywords: | Physical and Theoretical Chemistry, Organic Chemistry |
| Language: | English |
| Date: | 10 August 2020 |
| Deposited On: | 07 Sep 2020 16:04 |
| Last Modified: | 22 Jun 2025 01:37 |
| Publisher: | Wiley-Blackwell Publishing, Inc. |
| ISSN: | 1099-0690 |
| OA Status: | Hybrid |
| Publisher DOI: | https://doi.org/10.1002/ejoc.202000916 |
Haider, Victoria