González, Jorge A; Verdugo, Felipe; Mascareñas, José Luis; López, Fernando; Nevado, Cristina (2020). [C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights. Angewandte Chemie Internationale Edition, 59(45):20049-20054.
Pyridine‐substituted alkylidenecyclopropanes (Py‐ACPs) react with gold(III) salts under mild reaction conditions through an unprecedented, proximal ring‐opening pathway, to generate highly appealing, catalytically active pyridine alkenyl [C^N]‐gold(III) species. Mechanistic studies reveal that the activation of the C−C bond of the ACP takes place through an unusual concerted, σ‐bond metathesis type‐process.
Pyridine‐substituted alkylidenecyclopropanes (Py‐ACPs) react with gold(III) salts under mild reaction conditions through an unprecedented, proximal ring‐opening pathway, to generate highly appealing, catalytically active pyridine alkenyl [C^N]‐gold(III) species. Mechanistic studies reveal that the activation of the C−C bond of the ACP takes place through an unusual concerted, σ‐bond metathesis type‐process.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry |
| Uncontrolled Keywords: | General Chemistry, Catalysis |
| Language: | English |
| Date: | 2 November 2020 |
| Deposited On: | 09 Feb 2021 10:05 |
| Last Modified: | 27 Jan 2022 05:35 |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 1433-7851 |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.1002/anie.202007371 |
| PubMed ID: | 32671957 |
| Project Information: |
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González, Jorge A