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González, Jorge A; Verdugo, Felipe; Mascareñas, José Luis; López, Fernando; Nevado, Cristina (2020). [C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights. Angewandte Chemie Internationale Edition, 59(45):20049-20054.
Pyridine‐substituted alkylidenecyclopropanes (Py‐ACPs) react with gold(III) salts under mild reaction conditions through an unprecedented, proximal ring‐opening pathway, to generate highly appealing, catalytically active pyridine alkenyl [C^N]‐gold(III) species. Mechanistic studies reveal that the activation of the C−C bond of the ACP takes place through an unusual concerted, σ‐bond metathesis type‐process.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > General Chemistry |
| Uncontrolled Keywords: | General Chemistry, Catalysis |
| Language: | English |
| Date: | 2 November 2020 |
| Deposited On: | 09 Feb 2021 10:05 |
| Last Modified: | 11 Mar 2025 04:36 |
| Publisher: | Wiley-VCH Verlag |
| ISSN: | 1433-7851 |
| OA Status: | Green |
| Publisher DOI: | https://doi.org/10.1002/anie.202007371 |
| PubMed ID: | 32671957 |
| Project Information: |
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González, Jorge A