Pandiarajan, Devaraj; Fox, Thomas; Spingler, Bernhard (2021). An N4-Tetradentate Hydrazone Ligand That Binds in a Neutral, Mono- and Bisdeprotonated Form to Iron(II) and Zinc(II) Metal Ions. Crystals, 11(8):982.
The coordination chemistry of butane-2,3-dione bis (2′-pyridylhydrazone) towards the divalent first-row transition metals zinc and iron has been explored. Depending upon the conditions, the ligand in the six complexes was found to be either neutral, mono, or doubly deprotonated. The zinc(II) and iron(II) complexes were fully characterized by elemental analysis, mass spectrometry, and X-ray diffraction methods.
The coordination chemistry of butane-2,3-dione bis (2′-pyridylhydrazone) towards the divalent first-row transition metals zinc and iron has been explored. Depending upon the conditions, the ligand in the six complexes was found to be either neutral, mono, or doubly deprotonated. The zinc(II) and iron(II) complexes were fully characterized by elemental analysis, mass spectrometry, and X-ray diffraction methods.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > General Chemical Engineering
Physical Sciences > General Materials Science Physical Sciences > Condensed Matter Physics Physical Sciences > Inorganic Chemistry |
| Uncontrolled Keywords: | Inorganic Chemistry, Condensed Matter Physics, General Materials Science, General Chemical Engineering |
| Language: | English |
| Date: | 19 August 2021 |
| Deposited On: | 27 Aug 2021 07:12 |
| Last Modified: | 26 Sep 2023 01:44 |
| Publisher: | MDPI Publishing |
| ISSN: | 2073-4352 |
| OA Status: | Gold |
| Free access at: | Publisher DOI. An embargo period may apply. |
| Publisher DOI: | https://doi.org/10.3390/cryst11080982 |
Pandiarajan, Devaraj