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An N4-Tetradentate Hydrazone Ligand That Binds in a Neutral, Mono- and Bisdeprotonated Form to Iron(II) and Zinc(II) Metal Ions

Pandiarajan, Devaraj; Fox, Thomas; Spingler, Bernhard (2021). An N4-Tetradentate Hydrazone Ligand That Binds in a Neutral, Mono- and Bisdeprotonated Form to Iron(II) and Zinc(II) Metal Ions. Crystals, 11(8):982.

Abstract

The coordination chemistry of butane-2,3-dione bis (2′-pyridylhydrazone) towards the divalent first-row transition metals zinc and iron has been explored. Depending upon the conditions, the ligand in the six complexes was found to be either neutral, mono, or doubly deprotonated. The zinc(II) and iron(II) complexes were fully characterized by elemental analysis, mass spectrometry, and X-ray diffraction methods.

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > General Chemical Engineering
Physical Sciences > General Materials Science
Physical Sciences > Condensed Matter Physics
Physical Sciences > Inorganic Chemistry
Uncontrolled Keywords:Inorganic Chemistry, Condensed Matter Physics, General Materials Science, General Chemical Engineering
Language:English
Date:19 August 2021
Deposited On:27 Aug 2021 07:12
Last Modified:25 Jan 2025 02:40
Publisher:MDPI Publishing
ISSN:2073-4352
OA Status:Gold
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.3390/cryst11080982
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  • Content: Published Version
  • Language: English
  • Licence: Creative Commons: Attribution 4.0 International (CC BY 4.0)

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