Header

UZH-Logo

Maintenance Infos

An N4-Tetradentate Hydrazone Ligand That Binds in a Neutral, Mono- and Bisdeprotonated Form to Iron(II) and Zinc(II) Metal Ions


Pandiarajan, Devaraj; Fox, Thomas; Spingler, Bernhard (2021). An N4-Tetradentate Hydrazone Ligand That Binds in a Neutral, Mono- and Bisdeprotonated Form to Iron(II) and Zinc(II) Metal Ions. Crystals, 11(8):982.

Abstract

The coordination chemistry of butane-2,3-dione bis (2′-pyridylhydrazone) towards the divalent first-row transition metals zinc and iron has been explored. Depending upon the conditions, the ligand in the six complexes was found to be either neutral, mono, or doubly deprotonated. The zinc(II) and iron(II) complexes were fully characterized by elemental analysis, mass spectrometry, and X-ray diffraction methods.

Abstract

The coordination chemistry of butane-2,3-dione bis (2′-pyridylhydrazone) towards the divalent first-row transition metals zinc and iron has been explored. Depending upon the conditions, the ligand in the six complexes was found to be either neutral, mono, or doubly deprotonated. The zinc(II) and iron(II) complexes were fully characterized by elemental analysis, mass spectrometry, and X-ray diffraction methods.

Statistics

Citations

Dimensions.ai Metrics
2 citations in Web of Science®
2 citations in Scopus®
Google Scholar™

Altmetrics

Downloads

20 downloads since deposited on 27 Aug 2021
19 downloads since 12 months
Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > General Chemical Engineering
Physical Sciences > General Materials Science
Physical Sciences > Condensed Matter Physics
Physical Sciences > Inorganic Chemistry
Uncontrolled Keywords:Inorganic Chemistry, Condensed Matter Physics, General Materials Science, General Chemical Engineering
Language:English
Date:19 August 2021
Deposited On:27 Aug 2021 07:12
Last Modified:19 Aug 2022 10:00
Publisher:MDPI Publishing
ISSN:2073-4352
OA Status:Gold
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.3390/cryst11080982

Download

Gold Open Access

Download PDF  'An N4-Tetradentate Hydrazone Ligand That Binds in a Neutral, Mono- and Bisdeprotonated Form to Iron(II) and Zinc(II) Metal Ions'.
Preview
Content: Published Version
Language: English
Filetype: PDF
Size: 2MB
View at publisher
Licence: Creative Commons: Attribution 4.0 International (CC BY 4.0)