Brenig, Christopher; Mosberger, Leila; Blacque, Olivier; Kissner, Reinhard; Zelder, Felix (2021). Reversible metal-centered reduction empowers a Ni-Corrin to mimic F430. Chemical Communications, 57(59):7260-7263.
This communication presents a novel truncated NiII-containing metbalamin and describes its reversible one electron reduction to a catalytically active NiI species, that features cofactor F430 model character. Our results strikingly demonstrate that stabilization of NiI is not restricted to the related hydroporhyrinoid ligands and is of relevance to the application of metallocorrins in (biomimetic) catalysis.
This communication presents a novel truncated NiII-containing metbalamin and describes its reversible one electron reduction to a catalytically active NiI species, that features cofactor F430 model character. Our results strikingly demonstrate that stabilization of NiI is not restricted to the related hydroporhyrinoid ligands and is of relevance to the application of metallocorrins in (biomimetic) catalysis.
| Item Type: | Journal Article, refereed, original work |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials Physical Sciences > Ceramics and Composites Physical Sciences > General Chemistry Physical Sciences > Surfaces, Coatings and Films Physical Sciences > Metals and Alloys Physical Sciences > Materials Chemistry |
| Uncontrolled Keywords: | Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis |
| Language: | English |
| Date: | 1 January 2021 |
| Deposited On: | 13 Jan 2022 14:44 |
| Last Modified: | 27 Sep 2022 11:43 |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| OA Status: | Hybrid |
| Free access at: | Publisher DOI. An embargo period may apply. |
| Publisher DOI: | https://doi.org/10.1039/d1cc02945b |
Brenig, Christopher