Header

UZH-Logo

Maintenance Infos

Reversible metal-centered reduction empowers a Ni-Corrin to mimic F430


Brenig, Christopher; Mosberger, Leila; Blacque, Olivier; Kissner, Reinhard; Zelder, Felix (2021). Reversible metal-centered reduction empowers a Ni-Corrin to mimic F430. Chemical Communications, 57(59):7260-7263.

Abstract

This communication presents a novel truncated NiII-containing metbalamin and describes its reversible one electron reduction to a catalytically active NiI species, that features cofactor F430 model character. Our results strikingly demonstrate that stabilization of NiI is not restricted to the related hydroporhyrinoid ligands and is of relevance to the application of metallocorrins in (biomimetic) catalysis.

Abstract

This communication presents a novel truncated NiII-containing metbalamin and describes its reversible one electron reduction to a catalytically active NiI species, that features cofactor F430 model character. Our results strikingly demonstrate that stabilization of NiI is not restricted to the related hydroporhyrinoid ligands and is of relevance to the application of metallocorrins in (biomimetic) catalysis.

Statistics

Citations

Dimensions.ai Metrics
3 citations in Web of Science®
2 citations in Scopus®
Google Scholar™

Altmetrics

Downloads

17 downloads since deposited on 13 Jan 2022
4 downloads since 12 months
Detailed statistics

Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials
Physical Sciences > Ceramics and Composites
Physical Sciences > General Chemistry
Physical Sciences > Surfaces, Coatings and Films
Physical Sciences > Metals and Alloys
Physical Sciences > Materials Chemistry
Uncontrolled Keywords:Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Language:English
Date:1 January 2021
Deposited On:13 Jan 2022 14:44
Last Modified:26 Feb 2024 02:42
Publisher:Royal Society of Chemistry
ISSN:1359-7345
OA Status:Hybrid
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.1039/d1cc02945b
  • Content: Published Version
  • Licence: Creative Commons: Attribution 3.0 Unported (CC BY 3.0)