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Synergizing hole accumulation and transfer on composite Ni/CoOx for photoelectrochemical water oxidation


Wang, Wei; Heggen, Marc; Cui, Wei; Probst, Benjamin; Alberto, Roger; Cui, Chunhua (2020). Synergizing hole accumulation and transfer on composite Ni/CoOx for photoelectrochemical water oxidation. Chemical Communications, 56(70):10179-10182.

Abstract

Ni/CoOx sites were supported on an around 2 nm-TiOx modified hematite photoanode for water oxidation. TiOx demonstrates insignificant hole accumulation and a catalytically inactive surface that serves as an ideal platform. We reveal that the NiOx favors the extraction of holes from the TiOx surface, which are efficiently transferred to active CoOx for water oxidation.

Abstract

Ni/CoOx sites were supported on an around 2 nm-TiOx modified hematite photoanode for water oxidation. TiOx demonstrates insignificant hole accumulation and a catalytically inactive surface that serves as an ideal platform. We reveal that the NiOx favors the extraction of holes from the TiOx surface, which are efficiently transferred to active CoOx for water oxidation.

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Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Catalysis
Physical Sciences > Electronic, Optical and Magnetic Materials
Physical Sciences > Ceramics and Composites
Physical Sciences > General Chemistry
Physical Sciences > Surfaces, Coatings and Films
Physical Sciences > Metals and Alloys
Physical Sciences > Materials Chemistry
Uncontrolled Keywords:Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Language:English
Date:1 January 2020
Deposited On:16 Feb 2022 14:42
Last Modified:17 Feb 2022 21:05
Publisher:Royal Society of Chemistry
ISSN:1359-7345
OA Status:Closed
Publisher DOI:https://doi.org/10.1039/d0cc03717f
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