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Excited-state structure of copper phenanthroline-based photosensitizers


Guda, Alexander; Windisch, Johannes; Probst, Benjamin; van Bokhoven, Jeroen A; Alberto, Roger; Nachtegaal, Maarten; Chen, Lin X; Smolentsev, Grigory (2021). Excited-state structure of copper phenanthroline-based photosensitizers. Physical Chemistry Chemical Physics (PCCP), 23(47):26729-26736.

Abstract

Pump–probe XAS is used to catch the excited-state of two Cu photosensitizers and 4-coordinated excited states are observed. The exciplex can be involved in the deactivation of [Cu(dmp)$_{2}$]$^{+}$ as a non-observable state that forms slower than it decays.

Abstract

Pump–probe XAS is used to catch the excited-state of two Cu photosensitizers and 4-coordinated excited states are observed. The exciplex can be involved in the deactivation of [Cu(dmp)$_{2}$]$^{+}$ as a non-observable state that forms slower than it decays.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > General Physics and Astronomy
Physical Sciences > Physical and Theoretical Chemistry
Uncontrolled Keywords:Physical and Theoretical Chemistry, General Physics and Astronomy
Language:English
Date:1 January 2021
Deposited On:16 Feb 2022 15:16
Last Modified:28 Mar 2024 02:34
Publisher:Royal Society of Chemistry
ISSN:1463-9076
OA Status:Closed
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.1039/d1cp02823e
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