Fullerene Wires Assembled Inside Carbon Nanohoops

Abstract

Carbon-nanohoop structures featuring one or more round-shaped cavities represent ideal supramolecular hosts for spherical fullerenes, with potential to form host-guest complexes that perform as organic semiconductors in the solid state. Due to the tight complexation between the shape-complementary hosts and guests, carbon nanohoops have the potential to shield fullerenes from water and oxygen, known to perturb the electron-transport process. Many nanohoop receptors have been found to form host-guest complexes with fullerenes. However, there is only a little or no control over the long-range order of encapsulated fullerenes in the solid state. Consequently, the potential of these complexes to perform as organic semiconductors is rarely evaluated. Herein, we present a survey of all known nanohoop-fullerene complexes, for which the solid-state structures were obtained. We discuss and propose instances where the inclusion fullerene guests form discrete supramolecular wires, which might open up possibilities for their use in electronic devices.