Crystal structure of tris­(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris­(hexa­fluoro­phosphate) monohydrate

Abstract

The title compound, [Co(C72H48N6)](PF6)3·H2O, crystallizes with one tripositive complex mol­ecule, three hexa­fluoro­phosphate anions and one solvent mol­ecule of water in the asymmetric unit. The N6 coordination set around the central CoIII atom defines a distorted octa­hedral environment. Four fluorine atoms of one hexa­fluoro­phosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, inter­molecular π–π stacking inter­actions, C—H...π, C—H...F and O—H...F and inter­actions are present.