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Crystal structure of tris­(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris­(hexa­fluoro­phosphate) monohydrate


Mani, Asma; Belgaied, Jamel Eddine; Gasser, Gilles; Blacque, Olivier (2022). Crystal structure of tris­(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris­(hexa­fluoro­phosphate) monohydrate. Acta Crystallographica. Section E: Structure Reports Online, 78(3):313-316.

Abstract

The title compound, [Co(C72H48N6)](PF6)3·H2O, crystallizes with one tripositive complex mol­ecule, three hexa­fluoro­phosphate anions and one solvent mol­ecule of water in the asymmetric unit. The N6 coordination set around the central CoIII atom defines a distorted octa­hedral environment. Four fluorine atoms of one hexa­fluoro­phosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, inter­molecular π–π stacking inter­actions, C—H...π, C—H...F and O—H...F and inter­actions are present.

Abstract

The title compound, [Co(C72H48N6)](PF6)3·H2O, crystallizes with one tripositive complex mol­ecule, three hexa­fluoro­phosphate anions and one solvent mol­ecule of water in the asymmetric unit. The N6 coordination set around the central CoIII atom defines a distorted octa­hedral environment. Four fluorine atoms of one hexa­fluoro­phosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, inter­molecular π–π stacking inter­actions, C—H...π, C—H...F and O—H...F and inter­actions are present.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > General Chemistry
Physical Sciences > General Materials Science
Physical Sciences > Condensed Matter Physics
Uncontrolled Keywords:Condensed Matter Physics, General Materials Science, General Chemistry
Language:English
Date:1 March 2022
Deposited On:09 Jan 2023 17:29
Last Modified:28 Mar 2024 02:40
Publisher:International Union of Crystallography
ISSN:1600-5368
OA Status:Gold
Free access at:Publisher DOI. An embargo period may apply.
Publisher DOI:https://doi.org/10.1107/s2056989022001359
Project Information:
  • : FunderUniversity of Carthage
  • : Grant ID
  • : Project Title
  • : FunderTunisian Ministry of Higher Education and Scientific Research
  • : Grant ID
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  • Content: Published Version
  • Licence: Creative Commons: Attribution 4.0 International (CC BY 4.0)