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Mahe, Capucine; Blacque, Olivier; Gasser, Gilles; Gandon, Vincent; Cariou, Kevin (2023). N-Metallocenyl Ynamides: Preparation, Reactivity, and Synthesis of ansa[3]-Ferrocenylamides. Organic Letters, 25(4):624-629.
The first synthesis of various N-metallocenyl ynamides has been developed, and two strategies for the oxidative cyclization of N-ferrocenyl ynamide into ansa[3]-ferrocenylamide are also reported. The mechanism for the iodine(III)-triggered transformation has been studied by means of DFT calculations, showing that it proceeds through a concerted iodination deprotonation step.
| Item Type: | Journal Article, refereed, further contribution |
|---|---|
| Communities & Collections: | 07 Faculty of Science > Department of Chemistry |
| Dewey Decimal Classification: | 540 Chemistry |
| Scopus Subject Areas: | Life Sciences > Biochemistry
Physical Sciences > Physical and Theoretical Chemistry Physical Sciences > Organic Chemistry |
| Uncontrolled Keywords: | Organic Chemistry, Physical and Theoretical Chemistry, Biochemistry |
| Language: | English |
| Date: | 3 February 2023 |
| Deposited On: | 19 Jan 2024 14:32 |
| Last Modified: | 27 Feb 2025 02:38 |
| Publisher: | American Chemical Society (ACS) |
| ISSN: | 1523-7052 |
| OA Status: | Closed |
| Publisher DOI: | https://doi.org/10.1021/acs.orglett.2c04169 |
| PubMed ID: | 36688847 |
| Project Information: |
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Mahe, Capucine