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Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand


Besmer, Manuel Luca; Schwitter, Flurina; Battistin, Federica; Braband, Henrik; Fox, Thomas; Spingler, Bernhard; Alberto, Roger (2024). Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand. Dalton Transactions, 53(4):1434-1438.

Abstract

The fac–mer isomerisation in [MX$_{3}$(CO)$_{3}$]$^{2−}$ (M = Re, $^{99}$Tc) is induced by a PNP pincer-type ligand in the presence of a halide scavenger. The adaptation to the aqueous and saline chemistry of $^{99m}$Tc yields mer-[$^{99m}$Tc(PNP)(CO)$_{3}$]$^{+}$.

Abstract

The fac–mer isomerisation in [MX$_{3}$(CO)$_{3}$]$^{2−}$ (M = Re, $^{99}$Tc) is induced by a PNP pincer-type ligand in the presence of a halide scavenger. The adaptation to the aqueous and saline chemistry of $^{99m}$Tc yields mer-[$^{99m}$Tc(PNP)(CO)$_{3}$]$^{+}$.

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Additional indexing

Item Type:Journal Article, refereed, original work
Communities & Collections:07 Faculty of Science > Department of Chemistry
08 Research Priority Programs > Solar Light to Chemical Energy Conversion
Dewey Decimal Classification:540 Chemistry
Scopus Subject Areas:Physical Sciences > Inorganic Chemistry
Uncontrolled Keywords:Inorganic Chemistry
Language:English
Date:1 January 2024
Deposited On:17 Feb 2024 11:19
Last Modified:30 Jun 2024 03:31
Publisher:Royal Society of Chemistry
ISSN:1477-9226
OA Status:Hybrid
Publisher DOI:https://doi.org/10.1039/d3dt03992g
PubMed ID:38189151
  • Content: Published Version
  • Language: English
  • Licence: Creative Commons: Attribution 4.0 International (CC BY 4.0)